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Eclogite xenoliths from the Premier kimberlite, South Africa: geochemical evidence for a subduction origin

Department of Geological Sciences, University of Cape Town., Rondebosch, 7701, South Africa, e-mail: aleroex{at}geology.uct.ac.za; john.gurney{at}minserv.co.za

A suite of mantle eclogite hosted within the Premier kimberlite on the Kaapvaal craton can be classified on the basis of Na₂O content in garnets as group I type, although textures are ambiguous. No accessory phases of note occur, but rutile and phlogopite are found in a few samples. Clinopyroxenes show variable light rare element (LREE) enrichment (La/Yb_n = 2–48), and the garnets are strongly LREE depleted relative to chondrites (La/Yb_n = <0.04). Four pyroxenite samples include both garnet clinopyroxenite and garnet orthopyroxenite; clinopyroxenes in these samples are strongly LREE enriched (La/Yb_n = 57–65).

Calculated equilibration temperatures of the eclogites range from 999 ± 32 to 1168 ± 14° C with an average temperature of 1102 ± 37° C, assuming a pressure of 50 kbar. Relative to a shield geotherm of 40mW/m², these temperatures suggest a sampling depth of 135 to 165 km. A single, calcium-rich sample gives an equilibration temperature of 1296 ± 32° C at the same assumed pressure. Calculated equilibrium temperatures and pressures for the garnet pyroxenites are 887 to 987° C and 26 to 39 kbar (clinopyroxenite) and 1135 to 1156° C and 48 ± 2 kbar (orthopyroxenite).

Reconstituted bulk rock compositions of the eclogites indicate the presence of low- and high-MgO groups. The MgO-poor eclogites (8 to10.5 weight % MgO) have jadeite-rich clinopyroxenes and except for lower silica contents are similar to mid-ocean ridge basalts in major element composition, with slight negative Euanomalies (Eu/Eu*=0.83 to 0.96), indicative of (low-P) plagioclase fractionation. The MgO-rich eclogites (13.6 to 18 weight % MgO) are similar in composition to oceanic gabbro. In combination the geochemical data suggest that the Premier eclogite suite represents a fragment of a once composite oceanic crustal section; the protolith to the low-MgO eclogites was recycled oceanic crustal layer two metabasalt, which experienced silicic melt loss during subduction; the protolith to the high-MgO suite was oceanic crustal layer three cumulate gabbro/pyroxenite.